Sunan Abi Dawud 61
سنن أبي داود#61Sahihحَدَّثَنَا عُثْمَانُ بْنُ أَبِي شَيْبَةَ، حَدَّثَنَا وَكِيعٌ، عَنْ سُفْيَانَ، عَنِ ابْنِ عَقِيلٍ، عَنْ مُحَمَّدِ ابْنِ الْحَنَفِيَّةِ، عَنْ عَلِيٍّ، رضى الله عنه قَالَ قَالَ رَسُولُ اللَّهِ صلى الله عليه وسلم " مِفْتَاحُ الصَّلاَةِ الطُّهُورُ وَتَحْرِيمُهَا التَّكْبِيرُ وَتَحْلِيلُهَا التَّسْلِيمُ " .
Narrated Ali ibn AbuTalib: The key to prayer is purification; its beginning is takbir and its end is taslim
Scholarly Authentication
The label above is the grade most of these scholars gave — one dissenting opinion no longer speaks for all of them. If any scholar calls a narration fabricated, that verdict is shown instead, whatever the others say. Each scholar's own wording:
Al-AlbaniHasan Sahih
Muhammad Muhyi Al-Din Abdul HamidHasan Sahih
Zubair Ali ZaiHasan
In-book reference: 1:61